Food chemists uncover the secrets behind pretzels’ unique scent (2024)

Food Science

Researchers find 22 molecules that make chewy pretzels’ smell so tempting

by Laura Howes

June 20, 2019| A version of this story appeared inVolume 97, Issue 25

Food chemists uncover the secrets behind pretzels’ unique scent (1)

Credit: Shutterstock

Soft chewy pretzels have a unique smell wherever they are enjoyed.

Brezn, Brezeln, pretzels—whatever you call them, the knotted snacks smell different from other baked goods. Despite regional variations, all soft pretzels are chewy, salty, and have a shiny brown crust made by treating the uncooked dough with lye before baking. Sebastian Schoenauer and Peter Schieberle at the Technical University of Munich say that shiny crust is where the unique smell of pretzels—or they might say Brezn—comes from (J. Agric. Food Chem.2019, DOI: 10.1021/acs.jafc.9b02601).

The pair bought freshly baked pretzels from their local bakery and used gas chromatography/mass spectrometry and professional aroma assessors to identify the odor compounds in the crusts. They found 22 odor compounds that contributed to the beguiling scent, and then recreated the fragrance by dissolving the compounds in ethanol. The team next tweaked the recipe to try to find which molecules were key to the pretzel scent.

Food chemists uncover the secrets behind pretzels’ unique scent (2)

Phenylacetic acid, for example, is in pretzel crusts and hasn’t previously been found in other breads. But if Schoenauer and Schieberle removed phenylacetic acid from their lab-made pretzel perfume, their testers couldn’t smell the difference. After removing other scent molecules individually, the researchers found two molecules that are essential to the unique pretzel scent: 2-acetyl-1-pyrroline, which has a roasted smell, and 4-hydroxy-2,5-dimethyl-3(2H)-furanone, which has a caramel smell. These molecules are found in other bakery scents, but the difference, the researchers say, lies in the proportions of the molecules, and that is influenced by the chemistry that goes on as the lye-treated crust bakes.

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Food chemists uncover the secrets behind pretzels’ unique scent (2024)

FAQs

Food chemists uncover the secrets behind pretzels’ unique scent? ›

After removing other scent molecules individually, the researchers found two molecules that are essential to the unique pretzel scent: 2-acetyl-1-pyrroline, which has a roasted smell, and 4-hydroxy-2,5-dimethyl-3(2H)-furanone, which has a caramel smell.

What is the secret ingredient which makes a pretzel taste like a pretzel? ›

But it's the distinctive "pretzel" flavor that makes this bread extraordinary. That comes from dipping the shaped dough in an alkaline solution — traditionally a small amount of food-grade lye dissolved in water — before baking.

What is the science behind pretzels? ›

Here is the important part: the Maillard reaction, is accelerated in an alkaline environment. The lye, as well as the baking soda, increases the alkalinity of the surface of the pretzel and allows for a browning reaction between amino group and reducing sugars to occur.

What is the aroma of soft pretzels? ›

Additional experiments with the panelists revealed that 4-hydroxy-2,5-dimethyl-3(2H)-furanone, which has a caramel-like odor, and 2-acetyl-1-pyrroline -- a roasty, popcorn-like smell -- were the key contributors to the pretzel aroma profile.

What gives pretzels their unique flavor? ›

The answer lies in a brief dip in an alkaline water bath before baking. This bath essentially gelatinizes the outside of the pretzel, preventing it from fully “springing” during baking (as bread does) and giving pretzels their signature chewy crust. It also gives them their unique and indelible “pretzel” flavor.

Is lye in pretzels bad for your stomach? ›

To prepare, shaped pretzels are dipped in a lye bath, then baked in the oven. This method can also be used with rolls or buns. Once lye-dipped pretzels are baked, they're totally safe (and delicious!) to eat.

What gives pretzels their shine? ›

The Truth About Lye

It imparts that unique pretzel smell and taste by inhibiting the creation of typical baked-good aroma compounds while spurring the formation of others and also adds unmistakable mineral flavor. And it gels surface starch, so the pretzels bake up smooth and shiny.

Why do my pretzels smell like paint? ›

Rancid foods have the same look and texture as when they were purchased, but their smell and taste have changed. The odour is akin to wet cardboard, oil paint, wood varnish or play dough. Some people are offended by it and know to throw the product out, while others think that's just how the product normally smells.

What do pretzels do to your body? ›

Although pretzels are low-fat, they are also pretty paltry on the protein and fiber front, and they can be quite high in sodium and carbs. What's more, they rank high on the glycemic index, meaning they can quickly spike blood sugar levels.

Why do Germans eat pretzels? ›

In the centuries following, the pretzel made its way into history books and European culture. By 1440 the pretzel's form was a symbol of good luck, long life and prosperity. By 1450, Germans ate pretzels and hard-boiled eggs for dinner on Good Friday – the day of fasting.

What is the smell of pretzel? ›

After removing other scent molecules individually, the researchers found two molecules that are essential to the unique pretzel scent: 2-acetyl-1-pyrroline, which has a roasted smell, and 4-hydroxy-2,5-dimethyl-3(2H)-furanone, which has a caramel smell.

What flavor is voodoo pretzels? ›

Zapp's Voodoo Pretzel Stix

These pretzels are twisted so you get even more of our Voodoo Seasoning that delivers a sweet, spicy and uniquely Cajun flavor. Voodoo Stick pretzels put a spell on you with its salt and vinegar flavor with just the right hint of smoky BBQ sweetness.

Why do pretzels taste so good? ›

Salt is the most common seasoning, or topping, for pretzels, complementing the washing soda or lye treatment that gives pretzels their traditional skin and flavor acquired through the Maillard reaction.

What makes a pretzel bun taste like a pretzel? ›

Lye-dipped pretzels, or in this case, pretzel buns, have a distinctive flavour that is both savoury and slightly bitter. The lye, a strong alkaline solution, is used to give the pretzels their characteristic dark brown colour and chewy exterior.

What is the pretzel flavor? ›

Malt Syrup (the kind used for beer) and dipping them in a hot alkaline solution (baking soda or food grade lye and hot water) after baking for about 20–30 seconds gives a pretzel its characteristic flavor and distinctive brown coloring. The alkaline solution is a big contributor to the pretzel flavor.

Why does pretzel bread taste different? ›

The distinctive flavor of pretzel bread comes from the use of lye in the baking process, which gives it a slightly tangy and salty taste. This bread is often shaped into small rolls or larger loaves, making it versatile for various culinary applications.

What is unique about pretzel dough? ›

Soft pretzels are just a yeast bread is that formed into a pretzel shape. The one big difference in pretzel making, as opposed to a regular bread, is that pretzels are boiled and then baked. It is the boiling that gives the outside of the pretzel its beautiful golden brown color and uniquely crisp and chewy texture.

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